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S2:E66 All Out Battle! Luffy vs. Zoro, Mysterious Grand Duel!
First Aired: April 22, 2001
Runtime: 24 min
Luffy, who does not realize the town is full of bounty hunters, engages in a battle with Zoro after he discovers that Zoro attacked the townsfolk, while Mr. 5 and Miss Valentine head for Princess Vivi.
